DOE/Lawrence Berkeley National Laboratory

Surprising control over photoelectrons from a topological insulator

Plain-looking but inherently strange crystalline materials called 3D topological insulators (TIs) are all the rage in materials science. Even at room temperature, a single chunk of TI is a good insulator in the bulk, yet behaves like a metal on its surface.

Researchers find TIs exciting partly because the electrons that flow swiftly across their surfaces are "spin polarized": the electron's spin is locked to its momentum, perpendicular to the direction of travel. These interesting electronic states promise many uses – some exotic, like observing never-before-seen fundamental particles, but many practical, including building more versatile and efficient high-tech gadgets, or, further into the future, platforms for quantum computing.

A team of researchers from the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California at Berkeley has just widened the vista of possibilities with an unexpected discovery about TIs: when hit with a laser beam, the spin polarization of the electrons they emit (in a process called photoemission) can be completely controlled in three dimensions, simply by tuning the polarization of the incident light.

"The first time I saw this it was a shock; it was such a large effect and was counter to what most researchers had assumed about photoemission from topological insulators, or any other material," says Chris Jozwiak of Berkeley Lab's Advanced Light Source (ALS), who worked on the experiment. "Being able to control the interaction of polarized light and photoelectron spin opens a playground of possibilities."

The Berkeley Lab-UC Berkeley team was led by Alessandra Lanzara of Berkeley Lab's Materials Sciences Division (MSD) and UC Berkeley's Department of Physics, working in collaboration with Jozwiak and Zahid Hussain of the ALS; Robert Birgeneau, Dung-Hai Lee, and Steve Louie of MSD and UC Berkeley; and Cheol-Hwan Park of UC Berkeley and Seoul National University. They and their colleagues report their findings in Nature Physics

Strange electronic states and how to measure them

In diagrams of what physicists call momentum space, a TI's electronic states look eerily like the same kinds of diagrams for graphene, the single sheet of carbon atoms that, before topological insulators came along, was the hottest topic in the materials science world.

In energy-momentum diagrams of graphene and TIs, the conduction bands (where energetic electrons move freely) and valence bands (where lower-energy electrons are confined to atoms) don't overlap as they do in metals, nor is there an energy gap between the bands, as in insulators and semiconductors. Instead the "bands" appear as cones that meet at a point, called the Dirac point, across which energy varies continuously.

The experimental technique that directly maps these states is ARPES, angle-resolved photoemission spectroscopy. When energetic photons from a synchrotron light source or laser strike a material, it emits electrons whose own energy and momentum are determined by the material's distribution of electronic states. Steered by the spectrometer onto a detector, these photoelectrons provide a picture of the momentum-space diagram of the material's electronic structure.

Similar as their Dirac-cone diagrams may appear, the electronic states on the surface of TIs and in graphene are fundamentally different: those in graphene are not spin polarized, while those of TIs are completely spin polarized, and in a peculiar way.

A slice through the Dirac-cone diagram produces a circular contour. In TIs, spin orientation changes continuously around the circle, from up to down and back again, and the locked-in spin of surface electrons is determined by where they lie on the circle. Scientists call this relation of momentum and spin the "helical spin texture" of a TI's surface electrons. (Electron spin isn't like that of a spinning top, however; it's a quantum number representing an intrinsic amount of angular momentum.)

Directly measuring the electrons' spin as well as their energy and momentum requires an addition to ARPES instrumentation. Spin polarization is hard to detect and in the past has been established by firing high-energy electrons at gold foil and counting which way a few of them bounce; collecting the data takes a long time.

Jozwiak, Lanzara, and Hussain jointly led the development of a precision detector that could measure the spin of low-energy photoelectrons by measuring how they scatter from a magnetic surface. Called a spin time-of-flight analyzer, the device is many times more efficient at data collection.